HAYNES® 242® alloy for High-temperature Fluorine-Bearing Environments Tech Brief
For Excellent Resistance to High-Temperature Fluorine-Bearing Environments and Outstanding High-Temperature Strength
New from Haynes International, HAYNES® 242® alloy is a unique, age-hardenable Ni-Mo-Cr alloy that combines excellent resistance to high-temperature fluorine-bearing environments with outstanding strength. It is ideally suited for use in processes involving exposure to gaseous fluorine & HF, or molten fluoride salts, particularly where high strength up to 1300°F (705°C) is required. Areas of potential application include fluoro-polymer and fluoro-elastomer production, nuclear fuel processing, mineral and metals production, and hydrofluoric acid production/processing, among others. 242® alloy is available in a full range of forms in the as-solution-annealed condition, and is normally age-hardened before being placed in service. It may also be cold-worked and age-hardened to achieve exceptionally high strength levels while maintaining good ductility.
Nominal Composition
Nickel | Balance |
Molybdenum | 25 |
Chromium | 8 |
Iron | 2 max. |
Cobalt | 2.5 max. |
Manganese | 0.8 max. |
Silicon | 0.8 max. |
Aluminum | 0.5 max. |
Carbon | 0.03 max. |
Boron | 0.006 max. |
Copper | 0.5 max. |
Typical Tensile Properties, Plate
Test Temperature | 0.2%Yield Strength | Ultimate Tensile Strength | Elongation | |||
°F | °C | ksi | MPa | ksi | MPa | % |
RT | RT | 113 | 780 | 184 | 1270 | 38 |
800 | 425 | 80 | 555 | 156 | 1075 | 44 |
1000 | 540 | 70 | 480 | 145 | 1000 | 47 |
1200 | 650 | 76 | 525 | 137 | 945 | 38 |
1400 | 760 | 42 | 290 | 106 | 730 | 66 |
1600 | 870 | 40 | 275 | 69 | 475 | 56 |
1800 | 980 | 28 | 190 | 41 | 285 | 65 |
Typical Rupture Strength, Plate
Test Temperature | Typical Rupture Properties: Stress Required to Produce Rupture in Hours Shown | ||||||
100 h | 1,000 h | 10,000 h | |||||
°F | °C | ksi | MPa | ksi | MPa | ksi | MPa |
1000 | 540 | 160 | 1105 | 140 | 965 | 120 | 825 |
1100 | 595 | 130 | 895 | 110 | 760 | 93 | 640 |
1200 | 650 | 105 | 725 | 90 | 620 | 75 | 515 |
1300 | 705 | 86 | 595 | 69 | 475 | 35 | 240 |
1400 | 760 | 59 | 425 | 29 | 200 | 17 | 115 |
Typical Room Temperature Physical Properties
Physical Property | British Units | Metric Units |
Density |
0.327 lb/in3 |
9.06 g/cm3 |
Electrical Resistivity | 48.0 µohm-in | 122.0 µohm-cm |
Modulus of Elasticity |
33.2 x 106 psi |
229 GPA |
Thermal Conductivity |
75.7 Btu-in/ft2-h-°F |
11.3 W/m-°C |
Specific Heat | 0.092 Btu/lb-°F | 386 J/Kg-°C |
Environmental Resistance
Oxidation Resistance – Excellent to 1400°F (760°C)
Gaseous Fluorine & HF – Excellent to 1650°F (900°C)
Molten Chloride/Fluoride Salts – Excellent to 1650°F (900°C)
Chloride Stress Cracking Resistance – Excellent
Chlorination – Excellent in Reducing Environments
Hydrogen Embrittlement Resistance – Fair to Good