Media |
Concentration,
Percent by Weight |
Test
Temperature |
Average Corrosion Rate Per year, Mils* |
°F |
(°C) |
625 alloy |
C-22 alloy |
C-276 alloy |
G-30 alloy |
|
| Acetic Acid |
99 |
Boiling |
<1 |
Nil |
<1 |
1 |
|
| Ferric Chloride |
10 |
Boiling |
7325 |
1 |
2 |
- |
|
| Formic Acid |
88 |
Boiling |
9 |
<1 |
1 |
2 |
|
| Hydrochloric Acid |
1 |
Boiling |
1 |
3 |
13 |
1 |
| |
|
| |
1.5 |
Boiling |
353 |
14 |
32 |
- |
| |
|
| |
2 |
194 |
(90) |
Nil |
Nil |
1 |
- |
| |
|
| |
2 |
Boiling |
557 |
61 |
51 |
- |
| |
|
| |
2.5 |
194 |
(90) |
72 |
<1 |
12 |
- |
| |
|
| |
2.5 |
Boiling |
605 |
141 |
85 |
- |
| |
|
| |
10 |
Boiling |
642 |
400 |
288 |
2364 |
|
| Hydrochloric Acid + 42g/l Fe2(SO4)3 |
1 |
200 |
(93) |
238 |
2 |
41 |
803 |
|
| |
5 |
150 |
(66) |
2 |
2 |
5 |
557 |
|
| Hydrochloric Acid + 2% HF |
5 |
158 |
(70) |
123 |
59 |
26 |
97 |
|
| Hydrofluoric Acid |
2 |
158 |
(70) |
20 |
9 |
9 |
10 |
| |
|
| |
5 |
158 |
(70) |
16 |
14 |
10 |
11 |
|
P2O5
(Commercial Grade) |
39 |
185 |
(85) |
1 |
2 |
9 |
- |
|
44 |
240 |
(116) |
23 |
21 |
100 |
- |
| |
|
| |
52 |
240 |
(116) |
12 |
11 |
33 |
- |
|
| P2O5 + 2000 ppm Cl |
38 |
185 |
(85) |
2 |
1 |
12 |
- |
|
| P2O5 + 0.5% HF |
38 |
185 |
(85) |
9 |
7 |
45 |
- |
|
| Nitric Acid |
10 |
Boiling |
<1 |
<1 |
7 |
<1 |
| |
|
| |
65 |
Boiling |
21 |
134 |
888 |
5 |
|
| Nitric Acid + 6% HF |
5 |
140 |
(60) |
73 |
67 |
207 |
- |
|
| Nitric Acid + 25% H2SO4 + 4% NaCl |
5 |
Boiling |
713 |
12 |
64 |
- |
|
| Nitric Acid + 1% HCl |
5 |
Boiling |
1 |
<1 |
8 |
- |
|
| Nitric Acid + 2.5% HCl |
5 |
Boiling |
<1 |
2 |
21 |
- |
|
| Nitric Acid + 15.8% HCl |
8.8 |
126 |
(52) |
>10,000 |
4 |
33 |
14 |
|
| Sulfuric Acid |
10 |
Boiling |
37 |
12 |
19 |
31 |
| |
|
| |
20 |
150 |
(66) |
<1 |
<1 |
<1 |
- |
| |
|
|
20 |
174 |
(79) |
<1 |
1 |
3 |
<1 |
|
| |
20 |
Boiling |
91 |
33 |
39 |
54 |
| |
|
| |
30 |
150 |
(66) |
<1 |
<1 |
1 |
<1 |
| |
|
| |
30 |
174 |
(79) |
<1 |
3 |
4 |
<1 |
|
| |
30 |
Boiling |
227 |
64 |
55 |
60 |
| |
|
| |
40 |
100 |
(38) |
<1 |
<1 |
<1 |
<1 |
| |
|
| |
40 |
150 |
(66) |
1 |
<1 |
1 |
<1 |
| |
|
| |
40 |
174 |
(79) |
35 |
9 |
10 |
2 |
|
| |
50 |
100 |
(38) |
1 |
<1 |
Nil |
<1 |
| |
|
| |
50 |
150 |
(66) |
25 |
1 |
4 |
<1 |
| |
|
| |
50 |
174 |
(79) |
58 |
16 |
12 |
10 |
|
| |
60 |
100 |
(38) |
<1 |
<1 |
<1 |
<1 |
| |
|
| |
70 |
100 |
(38) |
<1 |
Nil |
Nil |
<1 |
| |
|
| |
80 |
100 |
(38) |
<1 |
Nil |
<1 |
- |
|
| Sulfuric Acid + 0.1% HCl |
5 |
Boiling |
151 |
26 |
33 |
- |
|
| Sulfuric Acid + 0.5% HCl |
5 |
Boiling |
434 |
61 |
49 |
- |
|
| Sulfuric Acid +1% HCl |
10 |
158 |
(70) |
121 |
<1 |
11 |
- |
| |
|
| |
10 |
194 |
(90) |
326 |
94 |
45 |
- |
| |
|
| |
10 |
Boiling |
869 |
225 |
116 |
- |
|
| Sulfuric Acid + 2% HF |
10 |
Boiling |
55 |
29 |
22 |
53 |
|
| Sulfuric Acid + 200 ppm Cl- |
25 |
158 |
(70) |
110 |
11 |
12 |
- |
|
| |
25 |
Boiling |
325 |
215 |
186 |
101 |
|
| Sulfuric Acid + 1.2% HCl + 1% FeCl3 + 1% CuCl2 |
11 |
Boiling |
1815 |
3 |
42 |
1227 |
|
| Sulfuric Acid + 1.2% HCl + 1% FeCl3 + 1% CuCl2 (ASTM G28B) |
23 |
Boiling |
2721 |
8 |
55 |
- |
|
| Sulfuric Acid + 42 g/l Fe2(SO4)3 (ASTM G28B) |
50 |
Boiling |
23 |
40 |
250 |
7 |
|
| * To convert mils per year (mpy) to mm per year, divide by 40.
|
|
|
|
|
Immersion Critical Pitting and Crevice-Corrosion Temperature in Oxidizing NaCl-HCl |
|
|
The chemical composition of the solution used in this test is as follows: 4% NaCl + 0.1% Fe2(SO4)3 + 0.01 M HCl. This solution contains 24,300 ppm chlorides and is acidic (pH2).
In both pitting and crevice-corrosion testing the solution temperature was varied in 5°C (9°F) increments to determine the lowest temperature at which pitting corrosion initiated (observed by examination at a magnification of 40X of duplicate samples) after a 24-hour exposure period (Critical Pitting Temperature), and the lowest temperature at which crevice-corrosion initiated in a 100-hour exposure period (Critical Crevice-Corrosion Temperature). |
|
Critical Pitting Temperature |
Critical Crevice-Corrosion Temperature |
Material |
°F |
°C |
°F |
°C |
|
| HASTELLOY® C-22® alloy |
>302 |
>150 |
212 |
102 |
| HASTELLOY C-276 alloy |
302 |
150 |
176 |
80 |
| HAYNES® 625 alloy |
194 |
90 |
122 |
50 |
| HASTELLOY G-30® alloy |
158 |
70 |
104 |
40 |
| FERRALIUM® 255 alloy |
122 |
50 |
95 |
35 |
| Alloy 904L |
113 |
45 |
68 |
20 |
| Type 317LM Stainless Steel |
95 |
35 |
59 |
15 |
| Type 317L Stainless Steel |
77 |
25 |
50 |
10 |
| Alloy 825 |
77 |
25 |
≤23 |
≤-5 |
| 20CB-3® alloy |
68 |
25 |
≤23 |
≤-5 |
| Type 316 Stainless Steel |
68 |
20 |
≤23 |
≤-5 |
|
Critical Pitting Temperatures in Oxidizing H2SO4-HCl Solution |
| The chemical composition of the solution used in this test is as follows: 11.5% H2SO4 + 1.2% HCl + 1% FeCl3 + 1% CuCl2. This test environment is a severely oxidizing acid solution which is used to evaluate the resistance of
alloys to localized corrosion. It is considerably more aggresive than the oxidizing NaCl-HCl test. Experiments were performed in increments of solution temperature of 5°C (9°F) for a 24-hour exposure period to determine the critical pitting temperature (the lowest temperature at which pitting corrosion initiated observed at a magnification of 40X of duplicate samples). |
| |
Critical Pitting Temperature |
| Material |
°F |
°C |
|
| HASTELLOY® C-22® alloy |
248 |
120 |
| HASTELLOY® C-276 alloy |
230 |
110 |
| HASTELLOY® C-4 alloy |
194 |
90 |
| HAYNES® 625 alloy |
167 |
75 |
|