A practical concern related to
an alloy’s susceptibility to inter-granular corrosion is the
heat-affected zone of weldments.
Welded test coupons of C-276
and C-22 alloys were exposed
to an oxidizing sulfuric acid process solution.* C-276 alloy
suffered unusually severe base
metal, weld metal, and heat-
affected zone attack in this particular environment. In fact only
one-third of the coupon thickness in the heat-affected zone survived the corrosion test.
C-276 alloy is seldom attacked
to this degree in other media.
There was minimal corrosion
attack on the C-22 alloy sample. |
 |
*11% H2SO4 + 3.9% Fe2(SO4)4
+ other chemicals at 302°F (150°C)
and overpressurized with O2 |
|
| Corrosion-Resistant Weld Filler Metal |
| Many corrosion failures are associated with welds. Reliable, cost effective and practical solutions to corrosion weld problems involve the use of HASTELLOY C-22 filler metal. Tests were conducted at the Los Alamos National Laboratory, New Mexico, in a simulated incinerator off-gas scrub solution for 39 days. Alloy 625 suffered severe base metal and weld metal attack in this particular environment. Moderate attack of the base
metal was observed on AL-6XN alloy. C-22 alloy exhibited no corrosion attack of the weld
metal and base metal. |
3M NaCl + 0.1M FeCl3 + 0.1M NaF 167°F (75°C), pH = 1 |
3M NaCl + 0.1M FeCl3 + 0.1M NaF
167°F (75°C), pH = 1 |
Alloy
|
Corrosion Rate
(mpy) |
Alloy
|
Corrosion Rate
(mpy) |
Base Metal |
Filler Weld |
Base Metal |
Filler Weld |
| AL-6XN |
625 |
112 |
625 |
625 |
100 |
| AL-6XN |
C-22 |
72 |
625 |
C-22 |
94 |
| C-22 |
C-22 |
0.17 |
|
 |
AL-6XN base 625 weld |
AL-6XN base C-22 weld |
|
625 base 625 weld |
625 base C-22 weld |
C-22 base C-22 weld |
| |
|
|