| Average Uniform Corrosion Resistance in Boiling Acids* |
|
|
|
Average |
|
|
Concentration |
Corrosion Rate Per Year |
Acid Medium |
|
Weight Percent |
Mils |
mm |
| Acetic Acid |
|
10 |
0.2 |
0.005 |
| |
|
30 |
0.2 |
0.005 |
| |
|
50 |
0.2 |
0.005 |
| |
|
70 |
0.2 |
0.005 |
| |
|
99 (Glacial) |
0.7 |
0.017 |
|
| Formic Acid |
|
10 |
0.4 |
0.010 |
| |
|
20 |
0.6 |
0.015 |
| |
|
30 |
0.6 |
0.015 |
| |
|
40 |
0.5 |
0.013 |
| |
|
60 |
0.3 |
0.008 |
| |
|
89 |
0.2 |
0.005 |
|
| Hydrochloric Acid |
|
1 |
0.3 |
0.005 |
| |
|
2 |
1.2 |
0.03 |
| |
|
5 |
3.8 |
0.10 |
| |
|
10 |
5.5 |
0.14 |
| |
|
15 |
8.6 |
0.22 |
| |
|
20 |
12.1 |
0.31 |
| |
(As-welded) |
20 |
13.6 |
0.35 |
| |
(50 ppm Fe+3) |
20 |
80.0 |
2.0 |
|
| Phosphoric Acid |
|
10 |
2.4 |
0.06 |
| (Chemically Pure) |
|
30 |
2.0 |
0.05 |
| |
|
50 |
3.0 |
0.08 |
| |
|
85 |
2.9 |
0.07 |
|
| Sulfuric Acid |
|
2 |
0.4 |
0.010 |
| |
|
5 |
0.7 |
0.018 |
| Phosphoric Acid |
|
10 |
0.8 |
0.020 |
| (Chemically Pure) |
|
20 |
1.2 |
0.03 |
| |
|
30 |
1.2 |
0.03 |
| |
(50 ppm Fe+3) |
30 |
18.8 |
0.48 |
| |
|
40 |
1.2 |
0.03 |
| |
|
50 |
1.7 |
0.04 |
| |
(As-welded) |
50 |
2.4 |
0.06 |
| |
(Aged 48 Hrs @ 1000°F (540°C)) |
50 |
2.0 |
0.05 |
| |
|
60 |
2.3 |
0.06 |
| |
|
70 |
6.6 |
0.17 |
|
|
* Data from three production heats, for material in the solution heat-treated condition, unless noted. Test values were determined from an average of four 24 hour exposures.
|
| Comparative Uniform Corrosion Resistance in Boiling Acids |
| |
Average Corrosion Rates Per Year, Mils (mm) |
| |
B-3® |
B-2 |
Type |
MONEL® 400 |
| Acid Medium |
alloy |
alloy |
316L |
alloy |
| 50% Acetic Acid |
0.2 |
(0.005) |
0.4 |
(0.010) |
0.2 |
(0.005) |
- |
|
| 40% Formic Acid |
0.5 |
(0.013) |
0.7 |
(0.018) |
41 |
(1.041) |
2.1 |
(0.053) |
| 50-55% Phosphoric Acid |
3.0 |
(0.076) |
6 |
(0.152) |
18 |
(0.457) |
4.5 |
(0.114) |
| 50% Sulfuric Acid |
1.7 |
(0.043) |
1.2 |
(0.030) |
>20,000 |
(>500) |
185 |
(4.699) |
| 20% Hydrochloric Acid |
12 |
(0.305) |
15 |
(0.381) |
>20,000 |
(>500) |
1587 |
(40.310) |
|
| Average Uniform Corrosion Resistance in HF Solutions* |
|
Average Corrosion Rates Per Year For Indicated Temperatures |
|
125°F (52°C) |
175°F (79°C) |
| % HF |
Mils |
mm |
Mils |
mm |
| 1 |
8.6 |
0.22 |
11.1 |
0.28 |
| 3 |
8.7 |
0.22 |
12.7 |
0.32 |
| 5 |
9.0 |
0.23 |
13.7 |
0.35 |
| 10 |
10.0 |
0.25 |
15.9 |
0.41 |
| 20 |
11.8 |
0.30 |
22.8 |
0.58 |
| 48 |
13.4 |
0.34 |
35.0 |
0.89 |
| 70 |
31.6 |
0.80 |
- |
- |
* Data from three production heats, for material in the solution heat-treated condition.
|
| Comparative Stress Corrosion Cracking Resistance |
U-Bend Specimens (ASTM G-30 Stress Method)
Boiling 60% H2SO4 |
|
|
HASTELLOY® B-3® alloy
Annealed + 1 hr at 1290°F (700°C)
(No cracking, 24 hours) |
HASTELLOY B-2 alloy
Annealed + 1 hr at 1290°F (700°C)
(Intergranular cracking, 3 hours) |
|
Flat, Sheet Specimens
Mill Annealed and Aged
1 Hour at 1290°F (700°C) |
Boiling
Solution |
B-2 alloy |
B-3 alloy |
| 5%H2SO4 |
IG-SCC |
NC** |
| 0.5%H2SO4 |
IG-SCC |
NC |
| 20%HCl |
IG-SCC |
NC |
* Intergranular stress-corrosion cracking at stamped identification sites.
** No Cracking |
|
|
| Effect of Cold Work Upon Corrosion Resistance in Boiling 20% HCl*
|
% |
Hardness |
Ultimate Tensile Strength |
Yield Strength at 0.2% Offset |
Elongation in 2" (51mm) |
Corrosion Rate Per Year |
Coldwork |
Rc |
Ksi |
MPa |
Ksi |
MPa |
% EL |
Mils |
(mm) |
0 |
18 |
125 |
860 |
62 |
425 |
57 |
13 |
(0.33) |
10 |
30 |
140 |
965 |
100 |
690 |
40 |
13 |
(0.33) |
20 |
37 |
159 |
1095 |
130 |
895 |
25 |
13 |
(0.33) |
30 |
41 |
180 |
1240 |
154 |
1060 |
13 |
13 |
(0.33) |
40 |
44 |
202 |
1395 |
172 |
1185 |
9 |
13 |
(0.33) |
50 |
46 |
221 |
1525 |
183 |
1260 |
8 |
13 |
(0.33) |
* Exposure for four 24 hour periods
|